Infrared spectroscopy of ionized corannulene in the gas phase

Infrared spectroscopy of ionized corannulene in the gas phase.

The gas-phase infrared spectra of radical cationic and protonated corannulene were recorded by infrared multiple-photon dissociation (IRMPD) spectroscopy using the IR free electron laser for infrared experiments. Electrospray ionization was used to generate protonated corannulene and an IRMPD spectrum was recorded in a Fourier-transform ion cyclotron resonance mass spectrometer monitoring H-los...

Gas-phase databases for quantitative infrared spectroscopy.

The National Institute of Standards and Technology (NIST) and the Pacific Northwest National Laboratory (PNNL) are each creating quantitative databases containing the vapor-phase infrared spectra of pure chemicals. The digital databases have been created with both laboratory and remote-sensing applications in mind. A spectral resolution of approximate, equals 0.1 cm(-1) was selected to avoid de...

Infrared Photodissociation Spectroscopy of Cluster Anions in the Gas Phase

Thermodynamic properties of the ionized gas 3He

In this article, we have calculated some thermodynamic properties for a system consisting of singy ionized 3He atoms and their corresponding removed electrons by employing the second quantization method at finite temperature. To perform the calculations, we have considered the kinetic term, and Coulomb interaction between the particles in our Hamiltonian. The calculated properties are free ener...

Long slit spectroscopy of diffuse ionized gas in NGC 55 ⋆

Spectroscopic measurements of emission line ratios and velocities are presented for ionized gas across the central plane of NGC 55, a late-type galaxy in the Sculptor group. The low metallicity in NGC 55 leads to relatively low line ratios of [S ii]/Hα and [N ii]/Hα for H ii regions as well as the diffuse ionized gas. These are the first spectroscopical measurements of line ratios in ionized ga...